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🌟Some Important Increasing Order 🌟:
🌟 1. Bond Angle :
(i) CH4 , C2H4 , C2H2
(ii) H2O, NH3 , CH4 , CO2
(iii) H2O, NH3 , CH4 , BH3
(iv) NO2—, NO2 , NO2+
(v) H2Se, H2S, H2O
(vi) AsH3 , PH3 , NH3
(vii) PF3 , PCl3 , PBr3 , PI3
(viii) NF3 , NCl3
(ix) NF3 , NH3 , NCl3
(x) OF2 , OH2 , Cl2O
🌟 2. Melting Point :
(i) Cs, Rb, K, Na, Li
(ii) Mg, Ba, Sr, Ca, Be
(iii) CaI2 , CaBr2 , CaCl2 , CaF2
(iv) BeCl2 , MgCl2 , CaCl2 , SrCl2 , BaCl2
(v) NaI, NaBr, NaCl, NaF
(vi) CsCl, RbCl, KCl, NaCl
(vii) AlCl3 , MgCl2 , NaCl
🌟 3.Boiling Point :
(i) PH3 , AsH3 , NH3 , SbH3
(ii) H2S, H2Se, H2O
(iii) HCl, HBr, HI, HF
(iv) NH3 , HF, H2O
(v) He, Ne, Ar, Kr
(vi) H2O, D2O
(vii) H2 , Cl2 , Br2
🌟 4.Dipole moments :
(i) CCl4 , CHCl3 , CH2Cl2 ,CH3Cl
(ii) NF3 , NH3 , H2O, HF
(iii) Cis-chloropropene, Trans-chloropropene
(iv) p, m, o-dichlorobenzene
(v) CH3I, CH3Br, CH3F, CH3Cl
(vi) NH3 , SO2 , H2O, HF
(vii) H2S, H2O
(viii) HI, HBr, HCl, HF
(ix) PH3 , ASH3 , SbH3 , NH3
(x) H2O, H2O2
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❤️Chemical and Ionic Equilibrium🤍
🥀Equilibrium
⚡️Equilibrium is the state of a process in which the properties like temperature, pressure, and concentration etc of the system do not show any change with passage of time.
➖In all processes which attain equilibrium, two opposing processes are involved.
➖Equilibrium is attained when the rates of the two opposing processes become equal.
➖If the opposing processes involve only physical changes, the equilibrium is called Physical Equilibrium.
➖If the opposing processes are chemical reactions, the equilibrium is called Chemical Equilibrium.
🥀Physical Equilibrium
➖Solid – liquid Equilibrium: H2O(s) = H2O(l)
➖Liquid – Gas Equilibrium: H2O(l) = H2O(g)
➖Solid – Solution Equilibrium: Salt(Solid) = Salt(in solution)
➖Gas –Solution equilibrium: CO2(g) = CO2(in solution)
🥀Equilibrium in Chemical Process
Reversible reaction:
⚡️A reaction in which not only the reactants react to form the products under certain conditions but also the products react to form reactants under the same conditions
🌷Examples:
3Fe(s) + 4H2O(g) \rightleftharpoons Fe3O4(s) + 4H2(g)
🥀Irreversible reaction:
⚡️A reaction cannot take place in the reverse direction, i.e. the products formed do not react to give back the reactants under the same condition.
🌷Example:
AgNO3(aq) + NaCl(aq) → AgCl(s) + NaNO3(g)
🥀Characteristics of Equilibrium State
⚡️It can be attained only if the reversible reaction is carried out in closed vessel.
⚡️It can be attained from either side of the reaction.
⚡️A catalyst can hasten the approach of equilibrium but does not alter the state of equilibrium.
⚡️It is dynamic in nature i.e. reaction does not stop but both forward and backward reactions take place at equal rate.
⚡️Change of pressure, concentration or temperature favours one of the reactions (forward or backward) resulting in shift of equilibrium point in one direction.
⚡️Law of Mass Action & Equilibrium Constant
“The rate at which a substance reacts is directly proportional to its active mass and rate of a chemical reaction is directly proportional to product of active masses of reactants each raised to a power equal to corresponding stoichiometric coefficient appearing in the balanced chemical equation”.
💫For reaction aA + bB \rightleftharpoons cC + dD
💫Rate of reaction ∝ Aa.Bb
💫or rate of reaction = KAaBb
⚡️where K is rate constant or velocity constant of the reaction at that temperature.
⚡️Unit of rate constant (K)
K = \frac{Rate\ of\ reaction}{A^aB^b}=\frac{molL^-^1 s^-^1}{(molL^1^)^a^+^b } = (molL^-^1)^1\ ^t^o\ ^n\ s^-^1
🥀Ionic Product:
a) Product of ionic concentration due to ions already present in water or from a salt.
b) I.P. may be and may not be equal to Ksp.
c) If ionic Product (IP) > Ksp ; precipitation takes place till I.P. equals Ksp
d) If Ionic Product < Ksp ; a precipitate will not be formed and the solution will be unsaturated.
e) If Ionic Product = Ksp ; a precipitate will not form an the solution is satuated in that salt.
#Point_to_remember 😇
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♨️💢Classification of solids as ionic, metallic, molecular, network (covalent) or amorphous.
(i) Tetra phosphdecoxide(P4O10) → Molecular
(ii) Ammonium phosphate(NH4)3PO4 → ionic
(iii) SiC → Network (Covalent)
(iv) I2 → molecular
(v) P4 → Molecular
(vi) Plastic → amorphous
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(viii) Brass → metallic
(ix) Rb → metallic
(x) LiBR → ionic
(xi) Si → Network (Covalent)
♨️💢Classification of solids as ionic, metallic, molecular, network (covalent) or amorphous.
(i) Tetra phosphdecoxide(P4O10) → Molecular
(ii) Ammonium phosphate(NH4)3PO4 → ionic
(iii) SiC → Network (Covalent)
(iv) I2 → molecular
(v) P4 → Molecular
(vi) Plastic → amorphous
(vii) Graphite → Network (Covalent)
(viii) Brass → metallic
(ix) Rb → metallic
(x) LiBR → ionic
(xi) Si → Network (Covalent)
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