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NEET Medical UG PG Notes, Ebooks, Free PDFs, Study Materials, Mock Tests, Videos. Promotion/Ads : @Pradhumn_Singh
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ORDER AND FACTS OF ORGANIC CHEMISTRY 💥
🔻1. RCOCl > RCOOCOR > RCOOR > RCONH2 Nucleophilic substitution reaction.
🔻2. HI > HBr > HCl > RCOOH > C6H5OH > H2O > CH CH > NH3 (Acidic nature).
🔻3. CCl3CHO > HCHO > CH3CHO > CH3COCH3 Nucleophilic addition reaction.
🔻4. CH2 = CH2 > CH CH > C6H6 Electrophilic addition reaction.
🔻5. (CH3)2C = C(CH3)2 > CH3 - CH = C -(CH3)2 > CH3 - CH = CH - CH3 > CH3 - CH = CH2 (Stability)
🔻6. NI3 > NBr3 > NCl3 > NF3 (Basic strength)
🔻7. Br2 > Cl2 > I2 (Selectivity for halogenation)
🔻8. Halogenation of alkenes by cyclic halonium state, so anti attack takes place.
🔻9.Hydroboration followed by oxidation is always anti markownikoff’s addition due to steric effect.
🔻10. Oximercuration -
demercuration is m.K. addition of water because some carbocation character in cyclic mercurium state.
🔻11CHCl3 in the presence of strong bases forms biradical : CCl2 which undergo addition with double or triple bonds.
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