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Repost from IIT JEE NEET NOTES

ORDER AND FACTS OF ORGANIC CHEMISTRY 💥 🔻1. RCOCl > RCOOCOR > RCOOR > RCONH2 Nucleophilic substitution reaction. 🔻2. HI > HBr > HCl > RCOOH > C6H5OH > H2O > CH CH > NH3 (Acidic nature). 🔻3. CCl3CHO > HCHO > CH3CHO > CH3COCH3 Nucleophilic addition reaction. 🔻4. CH2 = CH2 > CH CH > C6H6 Electrophilic addition reaction. 🔻5. (CH3)2C = C(CH3)2 > CH3 - CH = C -(CH3)2 > CH3 - CH = CH - CH3 > CH3 - CH = CH2 (Stability) 🔻6. NI3 > NBr3 > NCl3 > NF3 (Basic strength) 🔻7. Br2 > Cl2 > I2 (Selectivity for halogenation) 🔻8. Halogenation of alkenes by cyclic halonium state, so anti attack takes place. 🔻9.Hydroboration followed by oxidation is always anti markownikoff’s addition due to steric effect. 🔻10. Oximercuration - demercuration is m.K. addition of water because some carbocation character in cyclic mercurium state. 🔻11CHCl3 in the presence of strong bases forms biradical : CCl2 which undergo addition with double or triple bonds. Like 💛 | Comment 💌 | Share 🔗

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