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NECO GCE 2022 CHEMISTRY PRACTICAL ANSWERS
(1ai)
Tabulate
Burette reading/cm3 | 1st titre | 2nd titre
Final reading/cm3 | 22.50 | 22.50
Initial reading/cm3 | 0.00 | 0.00
Volume of A used/cm3 | 22.50 | 22.50
(1aii)
This is used for the easy identification of end-point or neutrality point.
(1aiii)
To avoid error in measurement which may occur through droplet of A into the burette affecting the reading
(1bi)
Mass conc. of A = 4.015/dm3
Mass conc. of B = 5.55/dm3
Volume of A, Va = 22.5cm3
Volume of B, Vb = 25.0cm3
Molar mass of A, Hcl = 1+35.5
= 36.5g/mol
:- Conc. of A in mol/dm3 = ??
Conc. of A (mol/dm3) = conc. Of A (g/dm3) ÷ molar mass
= 4.015/36.5
Conc. of A = 0.11mol/dm3
(1bii)
Conc. of B in mol/dm3 = ??
Cb = ??
Ca = 0.11mol/dm3, Va = 22.5cm3, V6 = 25.0cm3, na = 1, nb = 1
CaVa/CbVb = na/nb
Cb = CaVanb/naVa
Cb = 0.11x22.5x1/1x25.0
Cb = 2.475/25.0
Cb = 0.099mol/dm3
(1biii)
Molar mass of B = ??
ing Conc (mol/dm3) = conc. (g/dm3) ÷ molar mass
Molar mass = conc. (g/dm3) ÷ conc. (mol/dm3)
Molar mass = 5.55/0.099
Molar mass = 56.0g/mol
(1biv)
XOH = 56
X + 16 + 1 = 56
X + 17 = 56
X = 56 - 17
X = 39
(1c)
Potassium
(1cii)
It is an analytical value
(1ciii)
KOH
(1civ)
Potassium hydroxide
(2ai)
Is a soluble salt.
(2aii)
Ca²+ suspected.
(2aiii)
Ca2+ Present.
(2aiv)
Ppt remains insoluble.
(2av)
White Ppt formed which Remain insoluble
(2avi)
Brick red flame observed.
(2bi)
SO₂, H₂S Or CO₂ gas suspected
(2bii)
Lead(II) Ethanoate paper turns black
(2biii)
H₂s gas Evolved. S²- present
(3ai)
I - KMnO4
II - Bromine water
III - Litmus paper
(3aii)
(i) A rotten egg odour is perceived
(ii) A colourless gas is formed
(iii) A green coloured compound is formed
(3bi)
I:
- A precipitate is formed
- Asoluble xompound is also formed
II:
- Filtration
- Decantation
(3bii)
AgNO3 (silver trioxonitrate(v))
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